Transport Layer Security - ArchWiki
See also file:///usr/share/ca-certificates/trust-source/README
To extract the certificate stored in a .pfx file to a PEM file (if the it fails - append the -legacy option)
openssl pkcs12 -in cert.pfx -clcerts -out cert.pem [-legacy]
To extract also the private key (again - if this fails - append -legacy option)
openssl pkcs12 -in cert.pfx -nodes -out cert.pem [-legacy]
A pfx file is usually password protected, so input the password when challenged.
Copy the extracted file to
sudo cp cert.pem /usr/share/ca-certificates/trust-source/anchors/
And update the trust
sudo update-ca-trust